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vii) first- and second-order asymmetric transformationsa technique whereby diastereomers from the racemate equilibrate to yield a preponderance in solution of the diastereomer from the desired enantiomer or where preferential crystallization of the diastereomer from the desired enantiomer perturbs the equilibrium such that eventually in principle all the material is converted to the crystalline diastereomer from the desired enantiomer

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In pancreatic cancer, the ACSS2-mediated Zrt- and Irt-like protein 4 (ZIP4) signaling pathway reshapes metabolic activity by increasing the macropinocytosis of cancer cells and is positively associated with a poor prognosis [207]

This means that DNA adducts, which are repaired and appear in the urine, can be used as surrogate biomarkers of DNA damage Citation[119,120]