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1 H NMR (600 MHz, CDCl 3 ): 8.00 (s, 1H), 7.35 (s, 1H), 7.01 (t, J = 7.9 Hz, 1H), 6.89 (d, J = 8.0 Hz, 1H), 6.47 (d, J = 7.7 Hz, 1H), 5.685.53 (m, 1H), 5.02 (ddd, J = 17.2, 2.1, 0.9 Hz, 1H), 4.97 (dd, J = 10.2, 2.0 Hz, 1H), 3.88 (s, 3H), 3.76 (s, 3H), 3.71 (s, 3H), 3.313.24 (m, 1H), 3.243.14 (m, 1H), 3.122.99 (m, 4H), 2.78 (td, J = 11.7, 3.8 Hz, 1H), 2.60 (td, J = 11.2, 4.4 Hz, 1H), 2.352.25 (m, 1H), 2.11 (d, J = 12.1 Hz, 1H), 2.021.93 (m, 1H)

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While enhanced brain delivery may strengthen adaptive redox signaling pathways, excessive local accumulation or nanoparticle-induced surface reactivity may paradoxically intensify oxidative injury (162, 163)