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In vitro investigations have demonstrated that the aberrant activation of the MAPK signaling pathway in BRAF V600E-mutant TC can upregulate the production of DNMT1, thereby inducing hypermethylation of the TSHR promoter and leading to its transcriptional suppression [34, 35]

However, no structural information could be obtained for the non-canonical amino acids as these residues were either replaced or could not be 13 C, 15 N-labelled in the synthetic teixobactin and were thus inaccessible by ssNMR

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