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Mechanistically, finasteride has been proven to be 5-R2 inhibitor by acting on alternative substrate for 5-R2 which is initially bound to highly stable complex of enzyme-bound NADP-dihydrofinasteride

Metabolite Profiling of Hydroxycinnamate Derivatives in Plasma and Urine after the Ingestion of Coffee by Humans: Identification of Biomarkers of Coffee Consumption

Therefore, redox potentials do not translate into reaction velocities and nature does typically not rely on spontaneous equilibration between redox couples but on enzymatic catalysis

But individual response varies based on baseline glutathione status, genetic polymorphisms in glutathione synthesis enzymes, and concurrent medications that affect redox balance

Eid SA, Rumora AE, Beirowski B, Bennett DL, Hur J, Savelieff MG, Feldman EL

Mavrodi DV, Parejko JA, Mavrodi OV et al (2013) Recent insights into the diversity, frequency and ecological roles of phenazines in fluorescent Pseudomonas spp